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The European Physical Journal BISSN: 1434-6028 (printed version) Abstract Volume 1 Issue 3 (1998) pp 313-317 Scattering from small colloidal particles in a semidilute polymer solution
R.P. Sear (a)
FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands Received: 7 July 1997 / Received in final form: 12 November 1997 / Accepted: 19 November 1997 Abstract: The correlations between the segments of a semidilute polymer solution are found to induce correlations in the positions of small particles added to the solution. Small means a diameter much less than the polymer's correlation length. In the presence of polymer the particles behave as if they attracted each other. It is shown how the polymer's correlation length may be determined from a scattering experiment performed on the spheres.
PACS. 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling[:AND:] 83.70.Hq Heterogeneous liquids: suspensions, dispersions, emulsions, pastes, slurries, foams, block copolymers, etc.
(a) Present address: Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, CA 90024, USA email: sear@chem.ucla.edu Online publication: February 24, 1998 |